U.S. Biofuels Industry: A Critical Review of the Opportunities and Challenges

Authors

  • Min Chen The Pennsylvania State University
  • Paul M. Smith The Pennsylvania State University
  • Michael P. Wolcott Washington State University

Keywords:

Biofuels, Blend wall, Food vs. fuel, Renewable Fuel Standard (RFS), Low Carbon Fuel Standard (LCFS)

Abstract

Due to climate change concerns, governments and consumers are demanding increasing environmental accountability for transportation fuels, particularly as related to carbon emissions.  Additionally, the U.S. policymakers seek renewable alternatives to enhance energy security, reduce oil price volatility and increase rural economic development opportunities. These issues present an emerging market opportunity for lignocellulosic materials, while posing various challenges to industry scale-up. The review begins with first generation corn-grain ethanol and biodiesel, today’s most widely available biofuels within the U.S. Further growth of these biofuels may be limited by the “blend wall”, the “food-versus-fuel” debate, and land use change inssues. As a result, industrial, governmental and academic research interests have shifted to second and third generation biofuels produced from lignocellulosic biomass and algae to address GHG emissions and the food-fuel issue. Limiting factors to the scale-up of these hydrocarbon drop-in biofuels include feedstock costs and availability, high production and capital costs, policy uncertainty, and various technical, environmental and social issues.  This paper builds on previous literature and online secondary sources to present a comprehensive and current inventory of existing U.S. biofuel players, a thorough review of the U.S. biofuels industry and lessons learned from corn/grain ethanol applied to next generation lignocellulosic biofuels.

Author Biographies

Min Chen, The Pennsylvania State University

Fourth year Ph.D. Candidate of BioRenewables System (BRS)

Department of Agricultural and Biological Engineering

Paul M. Smith, The Pennsylvania State University

Professor of Bioproducts Marketing

BRS Graduate Program Coordinator

Department of Agricultural& Biological Engineering

Michael P. Wolcott, Washington State University

Louisiana-Pacific Distinguished Professor

Department of Civil & Environmental Engineering

References

Abengoa. (2014). Abengoa celebrates grand opening of its first commercial-scale next generation biofuels plant Retrieved July 19, 2015, from http://www.abengoa.com/web/en/novedades/hugoton/noticias/

AEC. (2013). Cellulosic biofuels industry progress report 2012-2013 (pp. 19). Washington DC: Advanced Ethanol Council.

AEC. (2015, January 15, 2015). Quad County, Syngenta join AEC Retrieved July 19, 2015, from http://advancedbiofuels.org/quad-county-syngenta-join-aec/#more-183

Aemetis. (2012, November 8, 2012). Biofuel producer Aemetis partners with Edeniq to implement advanced technology Retrieved July 19, 2015, from http://www.aemetis.com/biofuel-producer-aemetis-partners-with-edeniq-to-implement-advanced-technology/

Ahmed, S. (2008). Global food price inflation: implications for South Asia, policy reactions, and future challenges Policy research working paper 4796 (pp. 36). South Asia Region: The World Bank.

Ajanovic, A. (2011). Biofuels versus food production: Does biofuels production increase food prices? Energy, 36(4), 2070-2076. doi: http://dx.doi.org/10.1016/j.energy.2010.05.019

Algenol. (2016). About Algenol Retrieved February 19, 2016, from http://www.algenol.com/direct-to-ethanol/direct-to-ethanol

http://www.algenol.com/

AMG. (2013). Corn milling: Wet vs. Dry Retrieved May 7, 2014, from http://www.amg-eng.com/blog/corn-wet-milling-vs-dry-milling/

Amyris. (2015). Amyris fuels Retrieved August 25, 2015, from https://amyris.com/products/fuels/

Anonymous. (2010). Ethanol history - from alcohol to car fuel Retrieved July 26, 2015, from http://www.ethanolhistory.com/

Anonymous. (2014, April 29, 2014). Four commercial scale cellulosic ethanol biorefineries to enter production this year Retrieved December 10, 2014, from http://www.fuelsamerica.org/blog/entry/four-commercial-scale-cellulosic-ethanol-biorefineries-to-enter-production

AP. (2015). Demonstration facilities Retrieved July 19, 2015, from http://www.americanprocess.com/Default.aspx

Babcock, B. A. (2012). The impact of US biofuel policies on agricultural price levels and volatility. China Agricultural Economic Review, 4(4), 407-426.

Babcock, B. A., Marette, S., & Tréguer, D. (2011). Opportunity for profitable investments in cellulosic biofuels. Energy Policy, 39(2), 714-719.

Balan, V. (2014). Current challenges in commercially producing biofuels from lignocellulosic biomass. ISRN Biotechnology, 31.

Balan, V., Chiaramonti, D., & Kumar, S. (2013). Review of US and EU initiatives toward development, demonstration, and commercialization of lignocellulosic biofuels. Biofuels, Bioproducts and Biorefining, 7(6), 732-759. doi: 10.1002/bbb.1436

Bardhan, S. K., Gupta, S., Gorman, M., & Haider, M. A. (2015). Biorenewable chemicals: Feedstocks, technologies and the conflict with food production. Renewable and Sustainable Energy Reviews, 51, 506-520.

BFR. (2015). Fulton construction progress Retrieved July 19, 2015, from http://bfreinc.com/

Biodieselmagazine. (2015, January 7, 2016). USA plants. Biodiesel Magazine Retrieved January 29, 2016, from http://www.biodieselmagazine.com/plants/listplants/USA/

BiofuelsDigest. (2013). SuperData Retrieved March 16, 2014, from http://www.biofuelsdigest.com/bdigest/biofuels-digest-superdata/

Biomassboard. (2016). Federal activities report on the bioeconomy (pp. 46). Washington D.C.: The Biomass Research and Development (R&D) Board.

Bomb, C. (2005). Opportunities and barriers for biodiesel and bioethanol in Germany, the United Kingdom and Luxembourg. Master of Science in Environmental Management and Policy, Lund University, Lund, Sweden. Retrieved from http://lup.lub.lu.se/luur/download?func=downloadFile&recordOId=1322109&fileOId=1322110

BR. (2013). Projects/Alpha Retrieved July 19, 2015, from http://www.betarenewables.com/projects/3/alpha

Brancheau, J., Wharton, A., & Kamalov, F. (n.a.). The history of the automobile. The 20th century history class at New Vista High School Retrieved July 31, 2015, from http://l3d.cs.colorado.edu/systems/agentsheets/New-Vista/automobile/

Brennan, L., & Owende, P. (2010). Biofuels from microalgae—a review of technologies for production, processing, and extractions of biofuels and co-products. Renewable and Sustainable Energy Reviews, 14(2), 557-577.

Brown, T. R., & Brown, R. C. (2013). A review of cellulosic biofuel commercial-scale projects in the United States. Biofuels, Bioproducts and Biorefining, 7(3), 235-245. doi: 10.1002/bbb.1387

Buis, T. (2016). A year of success, despite overwhelming opposition. Ethanol Producer Magazine, 22, 12.

BusinessWire. (2012, June 4, 2012). Edeniq and Flint Hills Resources Renewables establish joint development relationship Retrieved July 19, 2015, from http://www.businesswire.com/news/home/20120604005516/en/Edeniq-Flint-Hills-Resources-Renewables-Establish-Joint#.VawCTPlViko

Butamax. (2013, October 2, 2013). Butamax technology Retrieved July 19, 2015, from http://www.butamax.com/renewable-fuel-technologies.aspx

Canergy. (2015). Project Retrieved July 19, 2015, from http://www.canergyus.com/project/

Carter, C. A., & Miller, H. I. (2012, July 30, 2012). Corn for food, not fuel Retrieved July 31, 2015, from http://www.nytimes.com/2012/07/31/opinion/corn-for-food-not-fuel.html?_r=0

Cheng, J. J., and Govinda R Timilsina. (2010). Advanced biofuel technologies: Status and barriers (D. R. G. E. a. E. Team, Trans.) Policy research working paper 5411 (pp. 47).

Cheng, J. J., & Timilsina, G. R. (2011). Status and barriers of advanced biofuel technologies: A review. Renewable Energy, 36(12), 3541-3549.

CoolPlanet. (2015). Drop-in renewable fuels & chemicals Retrieved August 25, 2015, from http://www.coolplanet.com/how-it-works/GreenFuels

Coskata. (2015). Facilities Retrieved July 19, 2015, from http://www.coskata.com/facilities/index.asp?source=4ACD6CB3-881C-4F31-BFDE-ED3A413BD2CE

Coyle, W. T. (2010). Next-generation biofuels: Near-term challenges and implications for agriculture. In USDA (Ed.), (pp. 26). Washington D.C.: DIANE Publishing.

Cuesta, J. (2014). Food price watch. In T. P. R. a. E. Department (Ed.), (pp. 10): The World Bank Group.

Dahmann, K. S., Fowler, L. B., & Smith, P. M. (2016, in press). United States Law and Policy and the Biofuel Industry. In Y. L. Bouthillier, A. Cowie, P. Martin & H. McLeod-Kilmurray (Eds.), The Law and Policy of Biofuels: Edward Elgar Publishing, IUCN Academy Series.

Daioglou, V., Stehfest, E., Wicke, B., Faaij, A., & Vuuren, D. P. (2015). Projections of the availability and cost of residues from agriculture and forestry. GCB Bioenergy, 1-15.

Dinneen, B. (2016). Record production propels industry in face of EPA rule. Ethanol Producer Magazine, 22, 10.

Dupont. (2015a). Advanced biofuels Retrieved July 19, 2015, from http://www.dupont.com/products-and-services/industrial-biotechnology/advanced-biofuels.html

DuPont. (2015b). The DuPont cellulosic ethanol facility in Nevada, Iowa: leading the way for commercialization Retrieved January 20, 2016, from http://www.dupont.com/products-and-services/industrial-biotechnology/advanced-biofuels/cellulosic-ethanol/nevada-iowa-cellulosic-ethanol-plant.html

EC. (2015, December 23, 2015). Paris Agreement. Climate Action Retrieved January 11, 2016, from http://ec.europa.eu/clima/policies/international/negotiations/future/index_en.htm

EERE. (2011). U.S. billion-ton update: crop residues and agricultural wastes. Washtington D.C.: USDOE Energy Efficiency & Renewable Energy Retrieved from https://www1.eere.energy.gov/bioenergy/pdfs/btu_crop_residues.pdf.

EERE. (2014a, March 14, 2014). Algal biofuels: long-term energy benefits drive U.S. research Retrieved February 17, 2016, from http://www.energy.gov/sites/prod/files/2014/03/f14/algal_biofuels_factsheet.pdf

EERE. (2014b). Biodiesel. Alternative fuels data center Retrieved April 1, 2014, from http://www.afdc.energy.gov/fuels/biodiesel.html

EERE. (2014c, December 16, 2014). Ethanol vehicle emissions. Alternative Fuels Data Center Retrieved January 20, 2016, from http://www.afdc.energy.gov/vehicles/flexible_fuel_emissions.html

EERE. (2015a, May 12, 2015). Biodiesel benefits and considerations Retrieved February 17, 2016, from http://www.afdc.energy.gov/fuels/biodiesel_benefits.html

EERE. (2015b, January 15, 2015). Biodiesel Vehicle Emissions. Alternative Fuels Data Center, from http://www.afdc.energy.gov/vehicles/diesels_emissions.html

EIA. (2011, September 14, 2011). The ethanol blend wall Retrieved March 16, 2014, from http://www.eia.gov/todayinenergy/detail.cfm?id=3070

EIA. (2014). International energy outlook 2014 (pp. 62). Washington D.C.: U.S. Energy Information Administration.

EIA. (2015). Annual energy outlook 2015 with projections to 2040 (pp. 154). Washington D.C.: U.S. Energy Information Administration (EIA).

EIA. (2016a). Monthly biodiesel production report (pp. 10). Washington D.C.: U.S. Energy Information Administration.

EIA. (2016b, February 2016). Monthly energy review Retrieved March 13, 2016, from http://www.eia.gov/totalenergy/data/monthly/#renewable; http://www.eia.gov/dnav/pet/hist/LeafHandler.ashx?n=PET&s=MGFUPUS1&f=A

EIA. (2016c, February 29, 2016). U.S. product supplied of finished motor gasoline Retrieved March 13, 2016, from http://www.eia.gov/dnav/pet/hist/LeafHandler.ashx?n=PET&s=MGFUPUS1&f=A

Emerald. (2015). Projects Retrieved August 25, 2015, from https://emeraldonellc-public.sharepoint.com/projects

Envergent. (2015). RTP for transportation Retrieved August 25, 2015, from https://www.envergenttech.com/technology/transporation-fuels/

EPA. (2014, March 16, 2014). EPA history: Clean Air Act Amendments of 1990 Retrieved Feb. 10, 2015, from http://www2.epa.gov/aboutepa/epa-history-clean-air-act-amendments-1990

EPA. (2015a). EPA proposes renewable fuel standards for 2014, 2015, and 2016, and the biomass-based diesel volume for 2017 (Vol. 80, pp. 4). Washington D.C.: Environmental Protection Agency.

EPA. (2015b, September 28, 2015). Program overview for Renewable Fuel Standard program Retrieved December 14, 2015, 2015, from http://www.epa.gov/renewable-fuel-standard-program/program-overview-renewable-fuel-standard-program

Ertl, D. (2013). Sustainable corn stover harvest (pp. 18): The Iowa Corn Promotion Board.

EuBP. (2013). Bioplastics facts and figures (pp. 6). Berlin: European Bioplastics.

FAO. (2015). Radical shift in agriculture critical to making future food systems smarter, more efficient - UN Retrieved July 19, 2015, from http://www.un.org/apps/news/story.asp?NewsID=49835#.VavulPlVikq

Farrell, A. E., Plevin, R. J., Turner, B. T., Jones, A. D., O'hare, M., & Kammen, D. M. (2006). Ethanol can contribute to energy and environmental goals. science, 311(5760), 506-508.

Fiberight. (2015). Renewable fuel from MSW a reality Retrieved July 19, 2015, from http://fiberight.com/iowa/

FitzPatrick, M., Champagne, P., Cunningham, M. F., & Whitney, R. A. (2010). A biorefinery processing perspective: Treatment of lignocellulosic materials for the production of value-added products. Bioresource Technology, 101(23), 8915-8922.

Fulcrum. (2015). Sierra biofuels plant Retrieved August 25, 2015, from http://fulcrum-bioenergy.com/facilities/

Fulton, L., Morrision, G., Parker, N., Witcover, J., & Sperling, D. (2014). Three routes forward for biofuels: incremental, transitional, and leapfrog NextSTEPS white paper (pp. 42). Davis, CA: UCDavis Institute of Transportation Studies.

Gallagher, P. W., Dikeman, M., Fritz, J., Wailes, E., Gauthier, W., & Shapouri, H. (2003). Supply and social cost estimates for biomass from crop residues in the United States. Environmental and Resource Economics, 24(4), 335-358.

Gegg, P., Budd, L., & Ison, S. (2014). The market development of aviation biofuel: Drivers and constraints. Journal of Air Transport Management, 39, 34-40.

Geraldes Castanheira, É., Grisoli, R., Freire, F., Pecora, V., & Coelho, S. T. (2014). Environmental sustainability of biodiesel in Brazil. Energy Policy, 65, 680-691.

Gevo. (2015). Future -generation biocatalyst: cellulosic isobutanol Retrieved July 19, 2015, from http://www.gevo.com/about/our-business/our-science-and-technology/

Gnansounou, E., Panichelli, L., Dauriat, A., & Villegas, J. D. (2008). Accounting for indirect land-use changes in GHG balances of biofuels: Review of current approaches (pp. 22).

Golden, J. S., & Handfield, R. B. (2014). Opportunities in the emerging bioeconomy (pp. 34). Washington D.C.: USDA, Office of Procurement and Property Management.

Graham, R. L., Nelson, R., Sheehan, J., Perlack, R., & Wright, L. L. (2007). Current and potential US corn stover supplies. Agronomy Journal, 99(1), 1-11.

Gustafson, C. (2010, March 3, 2010). History of ethanol production and policy Retrieved July 26, 2015, from https://www.ag.ndsu.edu/energy/biofuels/energy-briefs/history-of-ethanol-production-and-policy

Hahn-Hägerdal, B., Galbe, M., Gorwa-Grauslund, M. F., Lidén, G., & Zacchi, G. (2006). Bio-ethanol – the fuel of tomorrow from the residues of today. Trends in Biotechnology, 24(12), 549-556.

Hanna, M. A., Isom, L., & Campbell, J. (2005). Biodiesel: Current perspectives and future. JOurnal of Scienfitic & Industrial Research, 64, 854-857.

Himmel, M. E., Ding, S.-Y., Johnson, D. K., Adney, W. S., Nimlos, M. R., Brady, J. W., & Foust, T. D. (2007). Biomass recalcitrance: engineering plants and enzymes for biofuels production. Science, 315(5813), 804-807.

Hoffman, L., & Baker, A. (2010). Market issues and prospects for U.S. distillers’ grains supply, use, and price relationships (pp. 37).

Economic Research Service: United States Department of Agriculture.

Hollinger, D. Y. (2008). Defining a landscape-scale monitoring tier for the North American Carbon Program. In C. M. Hoover (Ed.), Field measurements for forest carbon monitoring (pp. 3-16): Springer.

Houghton, J., Weatherwax, S., & Ferrell, J. (2005). Lignocellulosic biomass characteristics. Breaking the Biological Barriers to Cellulosic Ethanol: A Joint Research Agenda. Paper presented at the The Biomass to Biofuels Workshop, Rockville, MD. http://genomicscience.energy.gov/biofuels/2005workshop/2005low_lignocellulosic.pdf

Howell, S. A., & Weber, J. A. (1995). U.S. biodiesel overview (pp. 9). Jefferson City, MO: National Biodiesel Board.

Hughes, S., Gibbons, W., & Kohl, S. (2009). Advanced Biorefineries for the Production of Fuel Ethanol. In A. Alain (Ed.), Biomass to Biofuels: Strategies for Global Industries (pp. 559). West Sussex, United Kingdom: 2010 John Wiley & Sons, Ltd.

Hughes, S. R., Gibbons, W. R., Moser, B. R., & Rich, J. O. (2013). Sustainable Multipurpose Biorefineries for Third-Generation Biofuels and Value-Added Co-Products. In Z. Fang (Ed.), Biofuels - Economy, Environment and Sustainability (pp. 245-267): InTech.

ICM. (2012). Cellulosic ethanol Retrieved July 19, 2015, from http://www.icminc.com/innovation/cellulosic-ethanol.html

INEOS. (2013, July 31, 2013). INEOS Bio produces cellulosic ethanol at commercial scale Retrieved July 20, 2015, from http://www.ineos.com/businesses/INEOS-Bio/News/INEOS-Bio-Produces-Cellulosic-Ethanol/

Jouleunlimited. (2014). Solar energy, liquefied Retrieved October 25, 2014, from http://www.jouleunlimited.com/about-joule

Lai, E. P. C. (2014). Biodiesel: Environmental friendly alternative to petrodiesel. Journal of Petroleum & Environmental Biotechnolgy, 5(1), 1-2.

Lane, J. (2014, July 24, 2014). Researchers find "Three Routes Forward for Biofuels" Retrieved January 20, 2016, from http://www.biofuelsdigest.com/bdigest/2014/07/24/researchers-find-three-routes-forward-for-biofuels/

Lane, J. (2015, July 29, 2015). Industry's withering critique of EPA's Renewable Fuel Standard proposals for 2014, 2015, 2016: the Digest version Retrieved January 21, 2016, from http://www.biofuelsdigest.com/bdigest/2015/07/29/industrys-withering-critique-of-epas-renewable-fuel-standard-proposals-for-2014-2015-2016-the-digested-version/

Langston, S., Collier, D., Wind, C. A., Nordberg, D., Capp, C. A., & Wendy, S. (2011). Final report: Oregon Low Carbon Fuel Standards. In D. Collier (Ed.), (pp. 174): State of Oregon Department of Environmental Quality.

LanzaTech. (2015). Lanza Tech jet fuel platform Retrieved August 25, 2015, from http://www.lanzatech.com/innovation/markets/fuels/

Lave, L. B., Burke, I. C., & Tyner, W. E. (2011). Renewable Fuel Standard: Potential economic and environmental effects of U.S. biofuel policy (pp. 417): National Research Council.

Lee, R. A. a. J. M. L. (2013). From first- to third-generation biofuels: Challenges of producing a commodity from a biomass of increasing complexity. Animal Frontiers, 3(2), 7-11.

Lidderdale, T. (2000). MTBE, oxygenates and motor gasoline (pp. 15). Washington D.C.: Energy Information Administration.

Martin, J. (2013). The blend wall and the future of the Renewable Fuels Standard (pp. 4). Washington DC: Union of Concerned Scientists.

Maverick. (2015). Products Retrieved August 25, 2015, from http://www.mavericksynfuels.com/about-us/overview/

MB. (2015). Meeting low-carbon fuel standards with California energy beets Retrieved July 20, 2015, from http://www.mendotabeetenergy.com/

Mohr, A., & Raman, S. (2013). Lessons from first generation biofuels and implications for the sustainability appraisal of second generation biofuels. Energy Policy, 63, 114-122.

Moser, B. R. (2011). Biodiesel production, properties, and feedstocks. In Vitro Cellular & Developmental Biology - Plant, 45(3), 229-266.

Naik, S. N., Goud, V. V., Rout, P. K., & Dalai, A. K. (2010). Production of first and second generation biofuels: A comprehensive review. Renewable and Sustainable Energy Reviews, 14(2), 578-597.

NBB. (2015a). History of biodiesel Retrieved August 1, 2015, from http://www.nbb.org/about-us/history-of-biodiesel-nbb

NBB. (2015b, 2015). NBB member plant maps Retrieved January 7, 2016, from http://biodiesel.org/production/plants/plant-maps

NBB. (2015c). Production statistics Retrieved July 30, 2015, from http://biodiesel.org/production/production-statistics

Nixon, R. (1973, November 7, 1973). Address to the nation about policies to deal with the energy shortages Retrieved January 8, 2016, from http://www.presidency.ucsb.edu/ws/?pid=4034

O'Brien, D. (2010). Updated trends in U.S. wet and dry corn milling production (pp. 8): Kansas State University.

Obama, B. (2015a). Fact sheet: President Obama to announce historic carbon pollution standards for power plants Retrieved January 29, 2016, from https://www.whitehouse.gov/the-press-office/2015/08/03/fact-sheet-president-obama-announce-historic-carbon-pollution-standards

Obama, B. (2015b, March 31, 2015). Fact sheet: U.S. reports its 2025 emissions target to the UNFCCC Retrieved July 31, 2015, from https://www.whitehouse.gov/the-press-office/2015/03/31/fact-sheet-us-reports-its-2025-emissions-target-unfccc

Olson, D. G., McBride, J. E., Shaw, A. J., & Lynd, L. R. (2012). Recent progress in consolidated bioprocessing. Current Opinion in Biotechnology, 23(3), 396-405.

Oltra, C. (2011). Stakeholder perceptions of biofuels from microalgae. Energy Policy, 39, 1774-1781.

Pacini, H., Sanches-Pereira, A., Durleva, M., Kane, M., & Bhutani, A. (2014). The state of the biofuels market: Regulatory, trade and development perspectives (pp. 101): UNCTAD: United Nations Conference on Trade and Development.

PB. (2015). History of biodiesel fuel Retrieved February 17, 2016, from http://www.biodiesel.com/biodiesel/history/

PB. (2016, 2016). Biodiesel benefits - why use biodiesel? Retrieved February 17, 2016, from http://www.biodiesel.com/biodiesel/benefits/

Piersol, R. (2011). Abenogoa loan guarantee leading to cellulosic ethanol production at York Retrieved July 19, 2015, from http://journalstar.com/business/local/abengoa-loan-guarantee-leading-to-cellulosic-ethanol-production-at-york/article_368a6d56-db5f-53d5-a753-96e95572b64d.html

Pimentel, D., & Patzek, T. W. (2005). Ethanol production using corn, switchgrass, and wood; biodiesel production using soybean and sunflower. Natural resources research, 14(1), 65-76.

POET-DSM. (2014, September 3, 2014). First commercial-scale cellulosic ethanol plant in the U.S. opens for business Retrieved July 19, 2015, from http://poet-dsm.com/pr/first-commercial-scale-cellulosic-plant

QCCP. (2015, April 24, 2015). About us Retrieved July 19, 2015, from http://www.quad-county.com/index.cfm?show=10&mid=4

Rabago, K. R. (2008). A review of barriers to biofuel market development in the United States. Environmental & Energy Law & Policy J., 2(2), 19.

RedRock. (2015). Advanced renewable biofuels Retrieved August 25, 2015, from http://www.redrockbio.com/

Regalbuto, J. R. (2009). Cellulosic biofuels–got gasoline. Science, 325(5942), 822-824.

RFA. (2013). Battling for the barrel. 2013 Ethanol Industry Outlook (pp. 30): Washington DC: Renewable Fuels Association.

RFA. (2014a). Falling walls & rising tides. 2014 Ethanol Industry Outlook (pp. 40): Washington DC: Renewable Fuels Association.

RFA. (2014b). World fuel ethanol production Retrieved March 13, 2014, from http://www.ethanolrfa.org/resources/industry/statistics/

RFA. (2015, November 13, 2015). Ethanol biorefinery locations Retrieved January 8, 2016, 2016, from http://www.ethanolrfa.org/resources/biorefinery-locations/

RFA. (2016, November 13, 2015). Industry statistics: Annual U.S. fuel ethanol production Retrieved March 13, 2016, from http://www.ethanolrfa.org/resources/industry/statistics/#1454099788442-e48b2782-ea53

Richard, T. L. (2010). Challenges in scaling up biofuels infrastructure. Science(Washington), 329(5993), 793-796.

Santacesaria, E., Vicente, G. M., Di Serio, M., & Tesser, R. (2012). Main technologies in biodiesel production: State of the art and future challenges. Catalysis Today, 195(1), 2-13.

Sapphire. (2014, 2014). What is green crude? Retrieved Dec. 12, 2014, from http://www.sapphireenergy.com/green-crude

Savage, N. (2011). Fuel options: the ideal biofuel. Nature, 474(7352), S9-S11.

Schill, S. R. (2016, February 2016). 2015 crop results - good quality, plentiful corn. Ethanol Producer Magazine, 22, 66.

Schmer, M. R., Vogel, K. P., Mitchell, R. B., & Perrin, R. K. (2008). Net energy of cellulosic ethanol from switchgrass. Proceedings of the National Academy of Sciences, 105(2), 464-469.

Schnepf, R. (2010). Agriculture-based biofuels: Overview and emerging issues (pp. 37). Washington DC: Congress Research Service.

Schnepf, R., & Yacobucci, B. D. (2013). Renewable fuel standard (RFS): Overview and issues. In Congress (Ed.), (pp. 35). Washington, D.C.: Congress Research Service.

Sheehan, J., T. Dunahay, J. Benemann, et al. . (1998). A look back at the U.S. Department of Energy's aquatic species proram - biodiesel from algae (pp. 4). Golden, CO: National Renewable Energy Laboratory.

Sheela, A. K. (2014, 11-18-2014). In terms of revenues, glycerol demand is set to hit USD 2.1 billion by 2018, growing at a CAGR of 7.7% from 2012 to 2018, 12-9-2014, from http://www.digitaljournal.com/pr/2342992

Sims, R., Taylor, M., Saddler, J., & Mabee, W. (2008). From 1st-to 2nd-generation biofuel technologies: An overview of current industry and RD&D activities (pp. 124): International Energy Agency Bioenergy.

Solazyme.com. (2014). Renewable fuels for the future Retrieved October 25, 2014, from http://solazyme.com/solutions/fuel/?lang=en

Solomon, B. D., Barnes, J. R., & Halvorsen, K. E. (2007). Grain and cellulosic ethanol: History, economics, and energy policy. Biomass and Bioenergy, 31(6), 416-425.

Srinivasan, S. (2009). The food v. fuel debate: A nuanced view of incentive structures. Renewable Energy, 34(4), 950-954.

Sundropfuels. (2015). Renewable advanced biofuels Retrieved August 25, 2015, from http://www.sundropfuels.com/Benefits/renewable-biofuels

Sweetwater. (2013a, December 18, 2013). Pacific Ethanol and Sweetwater Energy announce deal to supply customized industrial sugars to produce cellulosic ethanol Retrieved July 19, 2015, from http://www.sweetwater.us/pacific-ethanol-and-sweetwater-energy-announce-deal-to-supply-customized-industrial-sugars-to-produce-cellulosic-ethanol/

Sweetwater. (2013b, January 16, 2013). Second cellulosic ethanol deal announced: Sweetwater Energy and Front Range Energy sign 15-year, $100 million deal Retrieved July 19, 2015, from http://www.sweetwater.us/second-cellulosic-ethanol-deal-announced-sweetwater-energy-and-front-range-energy-sign-15-year-100-million-deal/

Sweetwater. (2013c). Sweetwater Energy and Ace Ethanol to begin commercial production of cellulosic ethanol Retrieved July 19, 2015, from http://www.sweetwater.us/sweetwater-energy-and-ace-ethanol-to-begin-commercial-production-of-cellulosic-ethanol/

SynTerra. (2012). Technology Retrieved August 25, 2015, from http://www.synterraenergy.com/technology/

Temesgen, H., Affleck, D., Poudel, K., Gray, A., & Sessions, J. (2015). A review of the challenges and opportunities in estimating above ground forest biomass using tree-level models. Scandinavian Journal of Forest Research, 30(4), 326-335.

Terrabon. (2008). MixAlco overview Retrieved August 25, 2015, from http://www.terrabon.com/mixalco_overview.html

Topsoe. (2015). Gasoline synthesis Retrieved August 25, 2015, from http://www.topsoe.com/processes/gasoline-synthesis

Urbanchuk, J. (2010). Background on Ethanol Current State of the U.S. Ethanol Industry (pp. 48). New Castle, DE: Cardno ENTRIX.

Urbanchuk, J. (2010). Current state of the U.S. ethanol industry (pp. 48). New Castle, DE: Cardno ENTRIX.

Virent. (2015). Products Retrieved August 25, 2015, from http://www.virent.com/products/

Wilhelm, W. W., Johnson, J. M., Karlen, D. L., & Lightle, D. T. (2007). Corn stover to sustain soil organic carbon further constrains biomass supply. Agronomy Journal, 99(6), 1665-1667.

Yeh, S., Sperling, D., Griffin, M., Khanna, M., Leiby, P., Msangi, S., . . . Rubin, J. (2012). National Low Carbon Fuel Standard: Policy design recommendations (pp. 81): Institute of Transportation Studies, University of California, Davis.

Yoon, J. J. (2011). What's the difference between biodiesel and renewable (green) diesel (pp. 14). Frederick, MD: Advanced Biofuels USA.

Yue, D., You, F., & Snyder, S. W. (2014). Biomass-to-bioenergy and biofuel supply chain optimization: Overview, key issues and challenges. Computers & Chemical Engineering, 66, 36-56.

Yusuf, N., Kamarudin, S., & Yaakub, Z. (2011). Overview on the current trends in biodiesel production. Energy Conversion and Management, 52(7), 2741-2751.

ZeaChem. (2012, October 12, 2012). ZeaChem completes construction of cellulosic ethanol biorefinery Retrieved July 20, 2015, from http://www.zeachem.com/press-releases/2015/4/8/zeachem-completes-construction-of-cellulosic-ethanol-biorefinery

Zhu, J. Y., Chandra, M. S., Gu, F., Gleisner, R., Reiner, R., Sessions, J., . . . Anderson, D. (2015). Using sulfite chemistry for robust bioconversion of Douglas-fir forest residue to bioethanol at high titer and lignosulfonate: A pilot-scale evaluation. Bioresource Technology, 179, 390-397.

Ziegler, J. (2008). Report of the special rapporteur on the right to food (pp. 4). Geneva, Switzerland: International Service for Human Rights.

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2016-07-06

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